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By Thomas J. Pinnavaia, M. F. Thorpe

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7. A. Corma and A. Martinez, Zeolites and zeotypes as catalysts, Adv. Mater. 7: 137 (1995). 8. B. J. W. B. Mower, Catalysis by crystalline aluminosilicates II. Molecular-shape selective reactions, J. Catal. 1: 307 (1962). 9. W. Vaughan, The synthesis and manufacture of zeolites, Chem. Eng. Prog. 2: 25 (1988). 10. E. Davis, New vistas in zeolite and molecular sieve catalysis, Acc. Chem. Rex. 26: 1 1 1 (1993). 1 1 . T. M. A. R. M. Flanigen, Aluminophosphate molecular sieves: a new class of microporous crystalline inorganic solids, J.

Van Bekkum, Catalysis of the tetrahydropyranylation of alcohols and phenols by the H-MCM-41 mesoporous molecular sieve, J. Chem. Res. (S) 1995, 26. 27 This page intentionally left blank. SYNTHESIS OF SURFACTANT-TEMPLATED MESOPOROUS MATERIALS FROM HOMOGENEOUS SOLUTIONS Mark T. Anderson, James E. O. Box 5800 Albuquerque, NM 87185 CLASSIFICATION OF POROUS MATERIALS Porous materials are grouped by IUPAC into three classes1 based on their pore diameters, d: (1) microporous - defined as d < 20 Å; (2) mesoporous - defined as 20 < d < 500 Å; and (3) macroporous - defined as d > 500 Å.

43. P. -X. E. Davis, Synthesis of titanium-containing ZSM-48, J. Chem. Soc. Chem, Commun. 1992, 745. 44. S. Rigutto and H. van Bekkum, Synthesis and characterization of a thermally stable vanadium-containing silicalite, Appl. Catal. H. V. Ramaswamy, and P. Ratnasamy, Synthesis and catalytic properties of crystalline, microporous vanadium silicates with MEL Structure, J. Catal. 137: 225 (1992). 45. A. T. Navarro, and J. Perez Pariente, Synthesis of an ultralarge pore titanium silicate isomorphous to MCM-41 and its application as a catalysts for selective oxidation of hydrocarbons, J.

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